Manganese Tricarbonyl Complexes with Asymmetric 2-Iminopyridine Ligands: Toward Decoupling Steric and Electronic Factors in Electrocatalytic CO2 Reduction
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چکیده
منابع مشابه
Electrocatalytic reduction of CO2 to CO by polypyridyl ruthenium complexes.
Electrocatalytic reduction of CO(2) by [Ru(tpy)(bpy)(solvent)](2+) (tpy = 2,2':6',2''-terpyridine, bpy = 2,2'-bipyridine) and its structural analogs is initiated by sequential 1e(-) reductions at the tpy and bpy ligands followed by rate limiting CO(2) addition to give a metallocarboxylate intermediate. It undergoes further reduction and loss of CO.
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ژورنال
عنوان ژورنال: Inorganic Chemistry
سال: 2016
ISSN: 0020-1669,1520-510X
DOI: 10.1021/acs.inorgchem.6b01477